Product ID:SOLVENT 111 DF
MSDS Date:02/01/1990
FSC:6810
NIIN:00-664-0388
MSDS Number: BWRWV

VULCAN MATERIALS CO

BIRMINGHAM, AL 35253-0689
US

Emergency Phone: 316-524-5751

Info Phone: 205-877-3459 / 415-821-5338

Cage: 1B637

VULCAN MATERIALS CO

530390 BIRMINGHAM, AL 35253 US

Telephone: 316-524-5751

Cage: 1B637

1,1,1 TRICHLOROEHANE (SARA 313) (CERCLA)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: >95%

OSHA PEL 350 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

GLYCOL METHYLENE ETHER

CAS: 646-06-0

RTECS: JR6760000

Fraction By Weight: <3%

SEC BUTANOL (SARA 313)

CAS: 78-92-2

RTECS: EO1750000

Fraction By Weight: <2%

OSHA PEL 150 PPM

1,2-BUTYLENE OXIDE (SARA 313) (CERCLA)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: <5%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Health Hazards Acute and Chronic:INHALE:MAJOR POTENTL ROUTE OF
EXPOSURE. MINIMAL EFFECTS OBSERVED<1,000PPM;DIZZY,DROWSY,& THROAT
IRRIT AT LEVELS>1, 000PPM;UNCONSCIOUSNESS & DEATH POSSIBLE AT
LEVELS>10,000PPM.BLOOD PRESSURE DEPRESSION ,CARDIAC SENSITIZATION &
VENTRICULAR ARRHYTHMIA CAN RESULT FROM EXPOSURE TO NEAR-ANESTHETIC
LEVELS. SKIN: PROLONGED
Effects of Overexposure:OR REPEATD CONTACT CAN CAUSE IRRIT,DEFAT
&DERMATITIS.ABSORPTN POSSIBLE IF CONTACT W/LIQ PROLONGD.EYE:LIQ CAN
CAUSE TEMP IRRIT W/SLIGHT TEMP CORNEAL INJURY.VAPOR CAN
IRRIT.INGEST:ASPIRATION INTO LUNG-C HEMICL PNEUMONIA &SYSTEMIC
EFFECTS.SECONDARY BUTANOL (PURE) CAUSED SEVERE CORNEAL INJURY
(RBBT)GI IRRIT &CNS DEPRESSN.

First Aid:INHAL:REMOVE TO FRESH AIR.IF BREATHING STOPPED,GIVE ARTIF
RESPRTN.CALL DR. SKIN:REMOVE CONTAMNTD CLOTHING & SHOES. WASH
EXPOSED AREA W/SOAP & WATER.WASH CONTAMNTD CLOTHING BEFORE REUSE.
EYE: FLUSH IMM ED W/WATER AT LEAST 15 MIN.IF IRRITATION
PERSISTS,CALL DR. INGEST: DON'T INDUCE VOMITING.CONTACT DR OR EMERG
MED FACILITY IMMED. NOTE TO DR:NO ADRENALIN TO PERSON OVEREXPOSD TO
1,1,1-TRICHLOROETHANE.

Flash Point Method:TOC
Flash Point:NONE
Lower Limits:7.5 @ 25C
Upper Limits:15.0 @ 25C
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE
Unusual Fire/Explosion Hazard:FIREFIGHTERS SHOULD WEAR SELF CONTAINED
POSITIVE PRESSURE BREATHING APPARATUS AND AVOID SKIN CONTACT.

Spill Release Procedures:EVACUATE,VENT & AVOID BREATHING VAPOR.DIKE.
CLEANUP (WEAR PROTECT EQUIP) BY MOPING OR W/ABSORBNT MAT'L & PLACE
IN CLSD CNTNR FOR DISPSOAL.AVOID CONTAMNTN OF GROUND/SURFACE
WATER.DON'T FLUSH TO SEWER I F SPILL INDOORS,TURN OFF
AIRCONDITION/HEATING SYST

Handling and Storage Precautions:STORE LABELED & SEALED CNTNRS IN
COOL,DRY, VENTED AREA. PREVENT WATER OR MOIST AIR FROM ENTERING
STORAGE TANKS OR CNTNRS.DO NOT CUT OR WELD ON DRUMS.
Other Precautions:ALUMINUM EQUIP SHOULD NOT BE USED FOR
STORAGE/TRANSFER. VAPOR HEAVIER THAN AIR,COLLECT IN LOW AREA.DON'T
ENTER CONFINED SPACE W/O FOLLOWING ENTRY PROCEDURES (ASTM
D-4276).CONTACT W/ALUMINUM PARTS IN P RESSURIZABLE FLUID SYSTEM MAY
CAUSE

Respiratory Protection:IF VAPOR CONCENTRATIONS EXCEED/LIKELY TO EXCEED
350 PPM,NIOSH/MSHA ORGANIC VAPOR TYPE RESPIRATOR
ACCEPTABLE.NIOSH/MSHA SCBA OR AIR LINE RESPRTR W/FULL FACEPIECE
REQ'D FOR VAPOR CONCENTRTNS>1,000PPM/ S PILLS/EMERG.FOLLOW RESPRTR
USE STDS/REGS
Ventilation:DO NOT USE IN CLOSED/CONFINED SPACE. OPEN DOORS/WINDOWS.
USE VENT TO MAINTAIN EXPOSURE LEVELS BELOW 350 PPM.
Protective Gloves:VITON,POLYVINYL ALCOHOL,EQUIVALENT
Eye Protection:SAFETY GLASSES,CHEM GOGGLES,FACESHLD
Other Protective Equipment:SOLVENT RESISTANT BOOTS, APRON, HEADGEAR
AND/ OR FACESHIELD SHOULD BE WORN WHERE SPLASHING IS POSSIBLE.
Work Hygienic Practices:AVOID CONTACT W/SKIN & BREATHING VAPOR.DON'T
EAT, DRINK,OR SMOKE IN WORK AREA.WASH HANDS PRIOR TO EAT,DRINK,USE
RESTROOM
Supplemental Safety and Health
VIOLENT REACTIONS. CONSULT EQUIPMENT SUPPLIER FOR FURTHER INFORMATION.
DO NOT REMOVE OR DEFACE LABEL. DO NOT REUSE DRUM WITHOUT RECYCLING
OR RECONDITIONING IN ACCORDANCE WITH ANY APPLICABLE FEDERAL, S
TATE, OR LOCAL LAWS.

HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100 @ 20C
Vapor Density:4.6
Spec Gravity:1.3 @ 25C
Evaporation Rate & Reference:0.4 (ETHER=1)
Solubility in Water:0.07 GM/100 GM @ 25C
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILDLY SWEET ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, OXIDIZERS, ALUMINUM AND OTHER REACTIVE METALS.
Stability Condition to Avoid:AVOID CONTACT WITH OPEN FLAME. ELECTRIC
ARCS, OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE
Conditions to Avoid Polymerization:AVOID CONTACT WITH OPEN FLAME,
ELECTRIC ARCS, OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL
DECOMPOSITION.

Waste Disposal Methods:RECOVERED LIQ MAY BE SENT TO A LICENSED
RECLAIMER OR INCINERATION FACILITY. CONTAMINATED MATERIAL MUST BE
DISPOSED OF IN A PERMITTED WASTE MANAGEMENT FACILITY. CONSULT
FEDERAL, STATE, OR LOCAL DISPOSA L AUTHORITIES FOR APPROVED
PROCEDURES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.